Continuous Water Absorption - Regeneration using Microbubble Technology for CO2 Removal in Biogas Upgrading System
Abstract
In this work, a system for upgrading biogas to biomethane was developed consisting of a continuous water absorption - regeneration using microbubble technology. The biogas upgrading system was tested using a 30% CO2–N2 simulated biogas. Microbubbles in the water absorbent were generated using a 0.5-inch venturi ejector before introducing into a gas separation unit. Various flow rates of the simulated biogas between 2 and 10 L/min were tested, at a constant water flow rate of 15 L/min, operating at pressure of 7 bar and their CO2 removal efficiency was monitored. The bubble bottle was initially tested the absorbent regeneration by distributing air into CO2 rich liquid to make CO2 desorption. The regeneration unit was designed to create a counter current between air and used water with air flow rates of 5–30 L/min. The optimum absorption conditions were found to be a liquid/gas ratio of 7.5 achieved with a simulated biogas flow rate of 2 L/min and 15 L/min water. An optimum air flow rate of 30 L/min in the regeneration unit produced a CO2 removal efficiency from the simulated biomethane of over 90%.
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Privalova E., Rasi S., Maki-Arvela P., Eranen K., Rintala J., and Murzin D.Y., 2013. CO2 capture from biogas: Absorbent selection, RSC Adv 3: 2979–2994. doi:10.1039/C2RA23013E.
Kohl A.L. and R. Nielsen, 1997. Gas Purification, Houston, Texas: Gulf Professional Publishing.
Dieter D. and S. Angelika, 2008. Biogas from waste and renewable resources: An Introduction. Weiheim, Germany: Wiley-VCH.
Abdeen R.H.F, Mel M., Jami M.S., Ihsan S.I., and Ismail, A.F., 2015. A review of chemical absorption of carbon dioxide for biogas upgrading. Chinese Journal of Chemical Engineering. doi: 10.1016/j.cjche.2016.05.006.
Xiao Y., Yuan H., Pang Y., Chen S., Zhu B., and Zou D., 2014. CO2 removal from biogas by water washing system. Chinese Journal of Chemical Engineering 22: 950–953. doi:10.1016/j.cjche.2014.06.001.
Takahashi M., 2005. Potential of microbubbles in aqueous solutions: Electrical properties of the gas–water interface. Journal of Physical Chemical 109(46): 21858–21864.
Takahashi M., Chiba K., and Li P., 2007. Free-radical generation from collapsing microbubbles in the absence of a dynamic stimulus. Journal of Physical Chemical 111(39): 11443–11446.
Poultonm D.J. and H.W. Baldwin, 1967. Oxygen exchange between carbonate and bicarbonate ions and water. I. Exchange in the absence of added catalysts. Canadian Journal of Chemistry 45(10): 1045-1050 Retrieved from the World Wide Web: https://doi.org/10.1139/v67-176.
Rotunno P., Lanzini A., and Leone P., 2017. Energy and economic analysis of a water scrubbing based biogas upgrading process for biomethane injection into the gas grid or use as transportation fuel. Renewable Energy 102: 417–432.
Khuntia S., Majumder S.K., and Ghosh P., 2012. Microbubble-aided water and wastewater purification: a review. Chemical Engineering 28: 191-221.
Sadatomi M., Kawahara A., Kano K., and Ohtomo A., 2005. Performance of a new micro-bubble generator with a spherical body in a flowing water tube. Experimental Thermal and Fluid Science 29: 615–623.
Dicker S., Mleczo M., Schmitz G., and Wrenn S.P., 2013. Size distribution of microbubbles as a function of shell composition. Ultrasonics 53: 1363–1367.
Korres N., Kiely P.O., Benzie A.H.J., and Jonathan S., 2013. Bioenergy production by anaerobic digestion: using agricultural biomass and organic wastes. London, England: Routledge.
Sebastian T., Marjut S., and Kristin O., 2014. Pre-evaluation of a new process for capture of CO2 using water. Research report VTT-R-04035-14.